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Aromatic Trifluoromethylselenolation via Pd-catalyzed C-H functionalization

Abstract : The synthesis of trifluoromethylselenolated aromatic molecules is described via an auxiliary-assisted, palladium catalyzed, C-H bonds functionalization with trifluoromethyl tolueneselenosulfonate as reagent. The mono-or bis-products can be preferentially formed. Some mechanistic investigations were realized to better understand the reaction. This methodology was also extended to fluoroalkylselenyl groups.
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https://hal.archives-ouvertes.fr/hal-03407550
Contributor : Thierry Billard Connect in order to contact the contributor
Submitted on : Thursday, October 28, 2021 - 3:08:49 PM
Last modification on : Tuesday, January 4, 2022 - 5:57:04 AM

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Kevin Grollier, Emmanuel Chefdeville, Erwann Jeanneau, Thierry Billard. Aromatic Trifluoromethylselenolation via Pd-catalyzed C-H functionalization. Chemistry - A European Journal, Wiley-VCH Verlag, 2021, 27 (50), pp.12910-12916. ⟨10.1002/chem.202102121⟩. ⟨hal-03407550⟩

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